2D sandwiches, artificial layered building blocks for multifunctional materials

This project aims to develop a new 2D sandwich structure with strong interlayer interactions to create multiferroic materials, enhancing material design flexibility and enabling advanced quantum material integration.

Subsidie
€ 1.975.955
2022

Projectdetails

Introduction

The possibility to create new materials bottom-up was enhanced via the stacking of atomically thin layers of two-dimensional (2D) materials with van der Waals interactions (vdWIs). Unfortunately, the downside of vdWIs is the, in general, weak electronic and mechanical interaction between the individual layers. This hinders the creation of multiferroic materials working at ambient conditions, which are, despite extensive research, still very scarce from stacked layers with vdWIs.

Research Objective

This research aims to create a new 2D building block: the 2D sandwich. This is a layered heterostructure with a strong interaction between the sandwich's individual layers mediated via an ionic or multivalent bond, whereas the interaction with other layers is still solely due to the vdWIs.

Prototype Functional Material

As the prototype functional material, a 2D magnetoelectric multiferroic sandwich composed of layered transition metal chalcogenides, oxides, or iodides will be grown using the modulated elemental reactants method.

Methodology

To tackle the possible sample degradation in the sandwiches, ultra-high vacuum optical surface science spectro-microscopy techniques will be developed to optically probe the 2D multiferroic sandwiches for both magnetism, ferroelectricity, and the coupling between them.

Open Samples Concept

The concept of open samples will be introduced, facilitating the scientific community with the straightforward verification of the data and accelerating the development of this new class of 2D sandwiches.

Material Design Strategies

This project will provide material design strategies that can remove the stringent lattice matching criteria to stack different classes of layered materials. It will also provide these classes of layered materials with similar stacking freedom as layered materials with vdWIs.

Insights and Interbreeding

These insights will allow the interbreeding of different classes of layered quantum materials, such as:

  1. Complex oxides
  2. 2D layered crystals with vdWIs
  3. Cuprate superconductors
  4. Topological insulators or semimetals

Financiële details & Tijdlijn

Financiële details

Subsidiebedrag€ 1.975.955
Totale projectbegroting€ 1.975.955

Tijdlijn

Startdatum1-10-2022
Einddatum30-9-2027
Subsidiejaar2022

Partners & Locaties

Projectpartners

  • FYZIKALNI USTAV AV CR V.V.Ipenvoerder

Land(en)

Czechia

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